{"id":68,"date":"2023-05-22T16:12:34","date_gmt":"2023-05-22T16:12:34","guid":{"rendered":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/?page_id=68"},"modified":"2023-06-01T15:22:14","modified_gmt":"2023-06-01T15:22:14","slug":"polarnano","status":"publish","type":"page","link":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/newresearch\/polarnano\/","title":{"rendered":"\u30de\u30eb\u30c1\u30b9\u30b1\u30fc\u30eb\u69cb\u9020\u89e3\u6790\u3067\u3042\u3076\u308a\u3060\u3057\u305f\u6975\u6027\u30ca\u30ce\u69cb\u9020"},"content":{"rendered":"\n<h3 class=\"wp-block-heading\">-\u89e3\u8aac-<\/h3>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"alignright size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/wp-content\/uploads\/2023\/05\/polarnano1-975x1024.jpg\" alt=\"\" class=\"wp-image-69\" width=\"448\" height=\"470\"\/><figcaption class=\"wp-element-caption\">\u56f31\u3000\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u9178\u7a92\u5316\u7269\u306e\u7d50\u6676\u69cb\u9020\uff08\u5de6\u4e0a\uff09\u3068\u96fb\u5b50\u5bc6\u5ea6\uff08\u53f3\u4e0a\uff09\u3001X\u7dda\u56de\u6298\u30d1\u30bf\u30fc\u30f3\uff08\u4e0b\uff09<\/figcaption><\/figure><\/div>\n\n\n<p>\u4eca\u56de\u306f\u3001\u9077\u79fb\u91d1\u5c5e\u9178\u7a92\u5316\u7269\u306e\u69cb\u9020\u306e\u304a\u8a71\u3067\u3059\u3002\u9077\u79fb\u91d1\u5c5e\u306e\u5468\u308a\u306b\u306f\u9178\u7d20\u3060\u3051\u304c\u914d\u4f4d\u3057\u3066\u3044\u308b\u3082\u306e\u304c\u591a\u3044\u3067\u3059\u304c\u3001\u9178\u7d20\u3068\u7a92\u7d20\u4e21\u65b9\u304c\u914d\u4f4d\u3057\u3066\u3044\u308b\u3082\u306e\u3082\u3042\u308a\u3001\u305d\u308c\u3092\u9178\u7a92\u5316\u7269\u3068\u547c\u3093\u3067\u3044\u307e\u3059\u3002\u6df7\u5408\u30a2\u30cb\u30aa\u30f3\u7cfb\u306e\u4e00\u7a2e\u3067\u5149\u89e6\u5a92\u3084\u9ad8\u8a98\u96fb\u4f53\u3001\u975e\u6bd2\u9854\u6599\u3068\u3057\u3066\u306e\u671f\u5f85\u304c\u3042\u308a\u307e\u3059\u3002NIMS\u306e\u5927\u6a4b\u6c0f\u304b\u3089LaTiO2N\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8(\u56f31\u5de6\u4e0a)\u3092\u3044\u305f\u3060\u3044\u3066\u89e3\u6790\u3057\u3066\u307f\u308b\u3068\u3001\u65e2\u5b58\u30e2\u30c7\u30eb\u3067\u306f\u8aac\u660e\u306e\u3064\u304b\u306a\u3044\u30d4\u30fc\u30af\u304c\u3042\u308a\u307e\u3057\u305f\u3002\u305d\u308c\u304c\u56f31\u306e044\/440\u30d4\u30fc\u30af\u306e\u3068\u3053\u308d\u3067\u3059\u3002\u3061\u306a\u307f\u306b\u3001\u3053\u306eX\u7dda\u30d7\u30ed\u30d5\u30a1\u30a4\u30eb\u306f1 \u00c5\u3068\u5c11\u3057\u9577\u3081\u306e\u6ce2\u9577\u3067\u6e2c\u5b9a\u3057\u3066\u3044\u307e\u3059\u3002\u7d50\u6676\u6027\u304c\u30d9\u30b9\u30c8\u3067\u306f\u306a\u3044\u306e\u3067\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u306b\u3059\u308b\u3068\u554f\u984c\u304c\u898b\u3048\u306a\u304f\u306a\u308b\u305f\u3081\u3067\u3059\u3002Fobs\u304c\u6b63\u78ba\u306b\u51fa\u306a\u3044\u554f\u984c\u306b\u60a9\u307f\u3064\u3064MEM\u96fb\u5b50\u5bc6\u5ea6\u89e3\u6790\u3059\u308b\u3068\u3001\u56f31\u53f3\u4e0a\u306e\u3088\u3046\u306a\u5f15\u304d\u4f38\u3070\u3055\u308c\u305f\u96fb\u5b50\u5bc6\u5ea6\u304c\u51fa\u3066\u304d\u307e\u3057\u305f\u3002\u3053\u308c\u304c\u3001044\/440\u306e\u4e0d\u4e00\u81f4\u306e\u539f\u56e0\u3068\u601d\u308f\u308c\u307e\u3057\u305f\u3002\u3068\u3053\u308d\u304c\u3001\u65e2\u5b58\u30e2\u30c7\u30eb\u306e\u90e8\u5206\u7fa4\u3067\u3044\u304f\u3089\u89e3\u6790\u3057\u3066\u3082\u3001\u3042\u3061\u3089\u3092\u7acb\u3066\u308c\u3070\u3053\u3061\u3089\u304c\u7acb\u305f\u305a\u72b6\u614b\u3067\u888b\u5c0f\u8def\u306b\u9665\u308a\u307e\u3057\u305f\u3002<\/p>\n\n\n\n<p><\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"alignleft size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/wp-content\/uploads\/2023\/05\/polarnano2-1024x586.jpg\" alt=\"\" class=\"wp-image-77\" width=\"550\" height=\"316\"\/><figcaption class=\"wp-element-caption\">\u56f32\u3000EXAFS\u306e\u52d5\u5f84\u5206\u5e03\uff08\u5de6\uff09\u3068\u9006\u30d5\u30fc\u30ea\u30a8\u632f\u5e45\uff08\u53f3\uff09\u56f3<\/figcaption><\/figure><\/div>\n\n\n<p>\u305d\u3053\u3067\u3001La\u5438\u53ce\u7aef\u3067EXAFS\u3092\u6e2c\u5b9a\u3057\u3066\u3001\u56f32\u5de6\u5074\u306eR\u30b9\u30da\u30af\u30c8\u30eb\u3092\u3055\u3089\u306bTi\u3068La\u30a8\u30ea\u30a2(La\u304b\u3089\u898b\u305f\u305d\u308c\u305e\u308c\u306e\u8ddd\u96e2\u570f)\u3067\u5207\u308a\u51fa\u3057\u3066\u3001\u9006\u30d5\u30fc\u30ea\u30a8\u5909\u63db\u3057\u3066\u307f\u307e\u3057\u305f\u3002\u3053\u308c\u306f\u3001\u4e0a\u8a18\u306e\u96fb\u5b50\u5bc6\u5ea6\u306e\u7570\u5e38\u304c\u3042\u3063\u305f\u304b\u3089\u3067\u3059\u3002\u3059\u308b\u3068\u3001\u56f32\u53f3\u306e\u3088\u3046\u306b\u30d3\u30fc\u30c8(\u304f\u3073\u308c)\u304c\u89b3\u6e2c\u3067\u304d\u307e\u3057\u305f\u3002\u30d3\u30fc\u30c8\u306f\u3001\u308f\u305a\u304b\u306a\u8ddd\u96e2\u5dee\u304b\u3089\u767a\u751f\u3059\u308b\u6ce2\u306e\u3046\u306d\u308a\u3067\u3059\u3002\u3053\u306e\u30d3\u30fc\u30c8\u306f\u65e2\u5b58\u30e2\u30c7\u30eb\u304b\u3089\u306e\u305a\u308c\u3092\u610f\u5473\u3057\u3066\u304a\u308a\u3001\u5c40\u6240\u7684\u306b\u306f\u3084\u306f\u308a\u4f4e\u5bfe\u79f0\u5316\u3092\u793a\u5506\u3057\u3066\u3044\u307e\u3059\u3002\u307e\u305f\u3001La\u306b\u89b3\u6e2c\u3055\u308c\u306a\u3044\u306e\u306f\u3001\u4e71\u308c\u3067\u306f\u306a\u3044\u3068\u3044\u3046\u3053\u3068\u3082\u793a\u3057\u3066\u3044\u307e\u3059\u3002\u3061\u306a\u307f\u306b\u6e2c\u5b9a\u306f31 K\u3001\u76f8\u8ee2\u79fb\u95a2\u4fc2\u306a\u304fEXAFS\u306f\u51b7\u3084\u3059\u3068\u683c\u6bb5\u306b\u30c7\u30fc\u30bf\u304c\u3088\u304f\u306a\u308b\u305f\u3081\u3067\u3059\u3002<\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"alignright size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/wp-content\/uploads\/2023\/05\/polarnano3-1024x733.jpg\" alt=\"\" class=\"wp-image-78\" width=\"565\" height=\"404\" srcset=\"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/wp-content\/uploads\/2023\/05\/polarnano3-1024x733.jpg 1024w, https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/wp-content\/uploads\/2023\/05\/polarnano3-300x215.jpg 300w, https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/wp-content\/uploads\/2023\/05\/polarnano3-768x550.jpg 768w, https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/wp-content\/uploads\/2023\/05\/polarnano3-1536x1100.jpg 1536w, https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/wp-content\/uploads\/2023\/05\/polarnano3.jpg 1909w\" sizes=\"(max-width: 565px) 100vw, 565px\" \/><figcaption class=\"wp-element-caption\">\u56f33\u3000\u4e2d\u6027\u5b50PDF\u89e3\u6790\u30018 \u212b\u4ee5\u4e0a\uff08\u5de6\u4e0a\uff09\u30688 \u212b\u4ee5\u4e0b\uff08\u5de6\u4e0b\uff09\u306b\u5206\u3051\u3089\u308c\u308b\u3002\u53f3\u306f\u6975\u6027\u30ca\u30ce\u69cb\u9020\u3002<\/figcaption><\/figure><\/div>\n\n\n<p>\u3088\u308a\u8a73\u7d30\u306a\u69cb\u9020\u3092\u898b\u305f\u3044\u3068\u601d\u3044\u3001\u4e2d\u6027\u5b50PDF(2\u4f53\u76f8\u95a2\u95a2\u6570)\u89e3\u6790\u3092\u884c\u3044\u307e\u3057\u305f\u3002PDF\u306f\u8ddd\u96e2\u30b9\u30b1\u30fc\u30eb\u3092\u5909\u3048\u3066\u89e3\u6790\u3067\u304d\u308b\u306e\u304c\u7279\u5fb4\u3067\u3059\u3002\u89e3\u6790\u3057\u3066\u3059\u3050\u306b\u9577\u8ddd\u96e2(\u56f33\u5de6\u4e0a\u30018-20 \u00c5)\u3067\u306f\u65e2\u5b58\u30e2\u30c7\u30ebImma\u3067\u5408\u3063\u3066\u3044\u3066\u3001\u30ca\u30ce\u30b9\u30b1\u30fc\u30eb(\u56f33\u5de6\u4e0b)\u3067\u306fImma\u30e2\u30c7\u30eb\u3067\u5408\u3063\u3066\u3044\u306a\u3044\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002Imma\u306e\u90e8\u5206\u7fa4\u306e\u4e2d\u304b\u3089\u96fb\u9855\u306e\u7d50\u679c\u3068\u6574\u5408\u3059\u308b\u30e2\u30c7\u30ebIma2\u3092\u69cb\u7bc9\u3059\u308b\u3068\u3001FIT\u304c\u304b\u306a\u308a\u6539\u5584\u3057\u307e\u3057\u305f\u3002\u56f33\u3067\u793a\u3057\u305fIma2\u69cb\u9020\u30e2\u30c7\u30eb\u306f\u3001\u96fb\u5b50\u5bc6\u5ea6\u3084EXAFS\u3068\u3082\u6574\u5408\u3057\u307e\u3059\u3002Ima2\u306f\u6975\u6027\u69cb\u9020\u3092\u6301\u3064\u305f\u3081\u3001\u5e73\u5747\u7684\u306b\u306fImma\u306enon-polar\u3067\u3082\u30ca\u30ce\u9818\u57df\u3067\u306fpolar\u3068\u3044\u3046\u308f\u3051\u3067\u3059\u3002\u30ea\u30e9\u30af\u30b5\u30fc\u3067\u89b3\u6e2c\u3055\u308c\u3066\u3044\u308b\u6975\u6027\u30ca\u30ce\u69cb\u9020\u3092\u898b\u51fa\u3057\u305f\u3068\u8a00\u3048\u305d\u3046\u3067\u3059\u3002\u305f\u3060\u3057\u3001\u30ea\u30e9\u30af\u30b5\u30fc\u306f\u5316\u5b66\u7684\u4e0d\u5747\u4e00\u304c\u8d77\u6e90\u3068\u8003\u3048\u3089\u308c\u3001\u9178\u7a92\u5316\u7269\u306e\u5834\u5408\u306fO\/N\u306e\u914d\u7f6e\u304c\u8d77\u6e90\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002O\/N\u306e\u914d\u7f6e\u3082\u3042\u308b\u7a0b\u5ea6\u7d5e\u308a\u8fbc\u3081\u3066\u3044\u307e\u3059\u304c\u5b8c\u5168\u3067\u306f\u306a\u3044\u306e\u3067\u3001\u3088\u308a\u8e0f\u307f\u8fbc\u3093\u3060\u30e2\u30c7\u30eb\u304c\u5fc5\u8981\u305d\u3046\u3067\u3059\u3002\u4eca\u56de\u306e\u89e3\u6790\u3067\u6c17\u3065\u3044\u305f\u306e\u306f\u3001\u30ca\u30ce\u306e\u6b6a\u304c\u5e73\u5747\u69cb\u9020\u306b\u73fe\u308c\u3066\u3044\u308b\u305f\u3081\u306b\u3001\u3053\u308c\u307e\u3067\u5e83\u304f\u8b70\u8ad6\u3055\u308c\u3066\u304d\u305fO\/N\u9577\u8ddd\u96e2\u79e9\u5e8f\u306e\u8b70\u8ad6\u306b\u554f\u984c\u304c\u3042\u308a\u305d\u3046\u306a\u3053\u3068\u3067\u3059\u3002\u4eca\u5f8c\u306f\u3001\u30de\u30eb\u30c1\u30d7\u30ed\u30fc\u30d6\/\u30de\u30eb\u30c1\u30b9\u30b1\u30fc\u30eb\u89e3\u6790\u3092\u6b66\u5668\u306b\u3053\u306e\u8fba\u3082\u660e\u3089\u304b\u306b\u3057\u3066\u3044\u3053\u3046\u3068\u601d\u3044\u307e\u3059\u3002\u4eca\u56de\u306e\u77e5\u898b\u3068\u6b21\u306e\u5408\u6210\u30b5\u30a4\u30af\u30eb\u306b\u6d3b\u304b\u3057\u305f\u3044\u3068\u601d\u3063\u3066\u3044\u307e\u3059\u3002<\/p>\n\n\n\n<p>\u53c2\u8003\u6587\u732e<br>[1] J. Yamaura et al., Chem. Commun. 56, 1385 (2020).<\/p>\n\n\n\n<p><\/p>\n","protected":false},"excerpt":{"rendered":"<p>-\u89e3\u8aac- \u4eca\u56de\u306f\u3001\u9077\u79fb\u91d1\u5c5e\u9178\u7a92\u5316\u7269\u306e\u69cb\u9020\u306e\u304a\u8a71\u3067\u3059\u3002\u9077\u79fb\u91d1\u5c5e\u306e\u5468\u308a\u306b\u306f\u9178\u7d20\u3060\u3051\u304c\u914d\u4f4d\u3057\u3066\u3044\u308b\u3082\u306e\u304c\u591a\u3044\u3067\u3059\u304c\u3001\u9178\u7d20\u3068\u7a92\u7d20\u4e21\u65b9\u304c\u914d\u4f4d\u3057\u3066\u3044\u308b\u3082\u306e\u3082\u3042\u308a\u3001\u305d\u308c\u3092\u9178\u7a92\u5316\u7269\u3068\u547c\u3093\u3067\u3044\u307e\u3059\u3002\u6df7\u5408\u30a2\u30cb\u30aa\u30f3\u7cfb\u306e\u4e00\u7a2e\u3067\u5149\u89e6\u5a92\u3084\u9ad8\u8a98\u96fb\u4f53\u3001\u975e\u6bd2\u9854\u6599\u3068\u3057\u3066\u306e\u671f\u5f85\u304c\u3042\u308a\u307e\u3059\u3002NIMS\u306e\u5927\u6a4b\u6c0f\u304b\u3089LaTiO2N\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8(\u56f31\u5de6\u4e0a)\u3092\u3044\u305f\u3060\u3044\u3066\u89e3\u6790\u3057\u3066\u307f\u308b\u3068\u3001\u65e2\u5b58\u30e2\u30c7\u30eb\u3067\u306f\u8aac\u660e\u306e\u3064\u304b\u306a\u3044\u30d4\u30fc\u30af\u304c\u3042\u308a\u307e\u3057\u305f\u3002\u305d\u308c\u304c\u56f31\u306e044\/440\u30d4\u30fc\u30af\u306e\u3068\u3053\u308d\u3067\u3059\u3002\u3061\u306a\u307f\u306b\u3001\u3053\u306eX\u7dda\u30d7\u30ed\u30d5\u30a1\u30a4\u30eb\u306f1 \u00c5\u3068\u5c11\u3057\u9577\u3081\u306e\u6ce2\u9577\u3067\u6e2c\u5b9a\u3057\u3066\u3044\u307e\u3059\u3002\u7d50\u6676\u6027\u304c\u30d9\u30b9\u30c8\u3067\u306f\u306a\u3044\u306e\u3067\u9ad8\u30a8\u30cd\u30eb\u30ae\u30fc\u306b\u3059\u308b\u3068\u554f\u984c\u304c\u898b\u3048\u306a\u304f\u306a\u308b\u305f\u3081\u3067\u3059\u3002Fobs\u304c\u6b63\u78ba\u306b\u51fa\u306a\u3044\u554f\u984c\u306b\u60a9\u307f\u3064\u3064MEM\u96fb\u5b50\u5bc6\u5ea6\u89e3\u6790\u3059\u308b\u3068\u3001\u56f31\u53f3\u4e0a\u306e\u3088\u3046\u306a\u5f15\u304d\u4f38\u3070\u3055\u308c\u305f\u96fb\u5b50\u5bc6\u5ea6\u304c\u51fa\u3066\u304d\u307e\u3057\u305f\u3002\u3053\u308c\u304c\u3001044\/440\u306e\u4e0d\u4e00\u81f4\u306e\u539f\u56e0\u3068\u601d\u308f\u308c\u307e\u3057\u305f\u3002\u3068\u3053\u308d\u304c\u3001\u65e2\u5b58\u30e2\u30c7\u30eb\u306e\u90e8\u5206\u7fa4\u3067\u3044\u304f\u3089\u89e3\u6790\u3057\u3066\u3082\u3001\u3042\u3061\u3089\u3092\u7acb\u3066\u308c\u3070\u3053\u3061\u3089\u304c\u7acb\u305f\u305a\u72b6\u614b\u3067\u888b\u5c0f\u8def\u306b\u9665\u308a\u307e\u3057\u305f\u3002 \u305d\u3053\u3067\u3001La\u5438\u53ce\u7aef\u3067EXAFS\u3092\u6e2c\u5b9a\u3057\u3066\u3001\u56f32\u5de6\u5074\u306eR\u30b9\u30da\u30af\u30c8\u30eb\u3092\u3055\u3089\u306bTi\u3068La\u30a8\u30ea\u30a2(La\u304b\u3089\u898b\u305f\u305d\u308c\u305e\u308c\u306e\u8ddd\u96e2\u570f)\u3067\u5207\u308a\u51fa\u3057\u3066\u3001\u9006\u30d5\u30fc\u30ea\u30a8\u5909\u63db\u3057\u3066\u307f\u307e\u3057\u305f\u3002\u3053\u308c\u306f\u3001\u4e0a\u8a18\u306e\u96fb\u5b50\u5bc6\u5ea6\u306e\u7570\u5e38\u304c\u3042\u3063\u305f\u304b\u3089\u3067\u3059\u3002\u3059\u308b\u3068\u3001\u56f32\u53f3\u306e\u3088\u3046\u306b\u30d3\u30fc\u30c8(\u304f\u3073\u308c)\u304c\u89b3\u6e2c\u3067\u304d\u307e\u3057\u305f\u3002\u30d3\u30fc\u30c8\u306f\u3001\u308f\u305a\u304b\u306a\u8ddd\u96e2\u5dee\u304b\u3089\u767a\u751f\u3059\u308b\u6ce2\u306e\u3046\u306d\u308a\u3067\u3059\u3002\u3053\u306e\u30d3\u30fc\u30c8\u306f\u65e2\u5b58\u30e2\u30c7\u30eb\u304b\u3089\u306e\u305a\u308c\u3092\u610f\u5473\u3057\u3066\u304a\u308a\u3001\u5c40\u6240\u7684\u306b\u306f\u3084\u306f\u308a\u4f4e\u5bfe\u79f0\u5316\u3092\u793a\u5506\u3057\u3066\u3044\u307e\u3059\u3002\u307e\u305f\u3001La\u306b\u89b3\u6e2c\u3055\u308c\u306a\u3044\u306e\u306f\u3001\u4e71\u308c\u3067\u306f\u306a\u3044\u3068\u3044\u3046\u3053\u3068\u3082\u793a\u3057\u3066\u3044\u307e\u3059\u3002\u3061\u306a\u307f\u306b\u6e2c\u5b9a\u306f31 K\u3001\u76f8\u8ee2\u79fb\u95a2\u4fc2\u306a\u304fEXAFS\u306f\u51b7\u3084\u3059\u3068\u683c\u6bb5\u306b\u30c7\u30fc\u30bf\u304c\u3088\u304f\u306a\u308b\u305f\u3081\u3067\u3059\u3002 \u3088\u308a\u8a73\u7d30\u306a\u69cb\u9020\u3092\u898b\u305f\u3044\u3068\u601d\u3044\u3001\u4e2d\u6027\u5b50PDF(2\u4f53\u76f8\u95a2\u95a2\u6570)\u89e3\u6790\u3092\u884c\u3044\u307e\u3057\u305f\u3002PDF\u306f\u8ddd\u96e2\u30b9\u30b1\u30fc\u30eb\u3092\u5909\u3048\u3066\u89e3\u6790\u3067\u304d\u308b\u306e\u304c\u7279\u5fb4\u3067\u3059\u3002\u89e3\u6790\u3057\u3066\u3059\u3050\u306b\u9577\u8ddd\u96e2(\u56f33\u5de6\u4e0a\u30018-20 \u00c5)\u3067\u306f\u65e2\u5b58\u30e2\u30c7\u30ebImma\u3067\u5408\u3063\u3066\u3044\u3066\u3001\u30ca\u30ce\u30b9\u30b1\u30fc\u30eb(\u56f33\u5de6\u4e0b)\u3067\u306fImma\u30e2\u30c7\u30eb\u3067\u5408\u3063\u3066\u3044\u306a\u3044\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002Imma\u306e\u90e8\u5206\u7fa4\u306e\u4e2d\u304b\u3089\u96fb\u9855\u306e\u7d50\u679c\u3068\u6574\u5408\u3059\u308b\u30e2\u30c7\u30ebIma2\u3092\u69cb\u7bc9\u3059\u308b\u3068\u3001FIT\u304c\u304b\u306a\u308a\u6539\u5584\u3057\u307e\u3057\u305f\u3002\u56f33\u3067\u793a\u3057\u305fIma2\u69cb\u9020\u30e2\u30c7\u30eb\u306f\u3001\u96fb\u5b50\u5bc6\u5ea6\u3084EXAFS\u3068\u3082\u6574\u5408\u3057\u307e\u3059\u3002Ima2\u306f\u6975\u6027\u69cb\u9020\u3092\u6301\u3064\u305f\u3081\u3001\u5e73\u5747\u7684\u306b\u306fImma\u306enon-polar\u3067\u3082\u30ca\u30ce\u9818\u57df\u3067\u306fpolar\u3068\u3044\u3046\u308f\u3051\u3067\u3059\u3002\u30ea\u30e9\u30af\u30b5\u30fc\u3067\u89b3\u6e2c\u3055\u308c\u3066\u3044\u308b\u6975\u6027\u30ca\u30ce\u69cb\u9020\u3092\u898b\u51fa\u3057\u305f\u3068\u8a00\u3048\u305d\u3046\u3067\u3059\u3002\u305f\u3060\u3057\u3001\u30ea\u30e9\u30af\u30b5\u30fc\u306f\u5316\u5b66\u7684\u4e0d\u5747\u4e00\u304c\u8d77\u6e90\u3068\u8003\u3048\u3089\u308c\u3001\u9178\u7a92\u5316\u7269\u306e\u5834\u5408\u306fO\/N\u306e\u914d\u7f6e\u304c\u8d77\u6e90\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002O\/N\u306e\u914d\u7f6e\u3082\u3042\u308b\u7a0b\u5ea6\u7d5e\u308a\u8fbc\u3081\u3066\u3044\u307e\u3059\u304c\u5b8c\u5168\u3067\u306f\u306a\u3044\u306e\u3067\u3001\u3088\u308a\u8e0f\u307f\u8fbc\u3093\u3060\u30e2\u30c7\u30eb\u304c\u5fc5\u8981\u305d\u3046\u3067\u3059\u3002\u4eca\u56de\u306e\u89e3\u6790\u3067\u6c17\u3065\u3044\u305f\u306e\u306f\u3001\u30ca\u30ce\u306e\u6b6a\u304c\u5e73\u5747\u69cb\u9020\u306b\u73fe\u308c\u3066\u3044\u308b\u305f\u3081\u306b\u3001\u3053\u308c\u307e\u3067\u5e83\u304f\u8b70\u8ad6\u3055\u308c\u3066\u304d\u305fO\/N\u9577\u8ddd\u96e2\u79e9\u5e8f\u306e\u8b70\u8ad6\u306b\u554f\u984c\u304c\u3042\u308a\u305d\u3046\u306a\u3053\u3068\u3067\u3059\u3002\u4eca\u5f8c\u306f\u3001\u30de\u30eb\u30c1\u30d7\u30ed\u30fc\u30d6\/\u30de\u30eb\u30c1\u30b9\u30b1\u30fc\u30eb\u89e3\u6790\u3092\u6b66\u5668\u306b\u3053\u306e\u8fba\u3082\u660e\u3089\u304b\u306b\u3057\u3066\u3044\u3053\u3046\u3068\u601d\u3044\u307e\u3059\u3002\u4eca\u56de\u306e\u77e5\u898b\u3068\u6b21\u306e\u5408\u6210\u30b5\u30a4\u30af\u30eb\u306b\u6d3b\u304b\u3057\u305f\u3044\u3068\u601d\u3063\u3066\u3044\u307e\u3059\u3002 \u53c2\u8003\u6587\u732e[1] J. Yamaura et al., Chem. Commun. 56, 1385 (2020).<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":62,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-68","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/pages\/68"}],"collection":[{"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/comments?post=68"}],"version-history":[{"count":5,"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/pages\/68\/revisions"}],"predecessor-version":[{"id":161,"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/pages\/68\/revisions\/161"}],"up":[{"embeddable":true,"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/pages\/62"}],"wp:attachment":[{"href":"https:\/\/yamaura-group.issp.u-tokyo.ac.jp\/index.php\/wp-json\/wp\/v2\/media?parent=68"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}